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Lead Orthophosphate, Pb3(PO4)2

The normal salt is precipitated by adding a dilute acetic acid solution of lead acetate to excess of a boiling solution of sodium hydrogen phosphate. If the precipitation takes place in the cold PbHPO4 is formed, but is changed into the normal phosphate by lengthened boiling with water; the latter salt is also slowly hydrolysed by boiling water. Lead phosphate is a yellow, amorphous powder, whose solubility in water amounts to 1.66×10-7 molecule per litre. It dissolves in caustic alkali solution.

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